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4.1.5 Synergistic mechanisms between plant phytochemicals and metal nanoparticles Plant-mediated metal nanoparticles have synergistic therapeutic effects that result from the interaction of metal cores (such as Au, Ag, Zn, and Mn) with bioactive phytochemicals (like flavonoids, alkaloids, and phenolics) (208)

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Notably, the PtMnIr nanozyme exhibits multiple enzymatic activities, integrating OXD, CAT, SOD, POD, and GPX functionalities, thereby promoting ferroptosis and apoptosis in tumour cells while inhibiting tumour metastasis by establishing an endogenous GSH consumptionROS cyclic generation mechanism [139]