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the pairs of enantiomers e.g., (S,S)/(R,R) the stereoisomers which are not mirror-images e.g., (S,S) and (R,S) are diastereomers

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There is an interesting parallel here because these three molecules, which were initially thought to be exclusively toxic, may in fact represent key regulators for various biological processes and in particular for signaling purposes, considering their relative stability, their capacity to diffuse across membranes (NO) and H 2 S are gases and the uncharged H 2 O 2 is channeled via aquaporins) and their propensity to react with thiolates ( H 2 O 2 -MEDIATED MODIFICATION OF PROTEIN THIOLS With methionines, cysteines are the most H 2 O 2 -sensitive residues

Sensitivity to carcinogenesis is increased and chemoprotective efficacy of enzyme inducers is lost in nrf2 transcription factor-deficient mice

In fact, it is so effective that Japan uses it almost exclusively to treat B12 deficiency

and German Federal Ministry of Education and Research