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Chemical Synthesis of Interleukin-2 and Disulfide Stabilizing Analogues

doi:10.1177/0194599818762383 Kent DT, Carden KA, Wang L, Lindsell CJ, Ishman SL

The paraffin was removed using xylene, and the sections were stained following the hematoxylin and eosin (H&E) staining protocol

Traditional antioxidants like vitamins C and E function through electron donation, essentially "sacrificing" themselves to neutralize free radicals

Although the reaction of PhSeBr and 1a generating the SeN intermediate INT1-Se is endothermic by 12.6 kcal mol 1 , INT1-Se may readily undergo a Se-centred [2,3]-sigmatropic rearrangement to generate an ortho -Se = N substituted dearomatized species ( INT2-Se ) via TS1-Se , with a barrier of 12.7 kcal mol 1