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While these bacterial enzymes have been explored for the generation of natural product analogs or applications in biocatalysis, the broad utility of amide bond-forming enzymes in enzymatic combinatorial synthesis has not been fully realized because of unwanted cross-reactivities of the enzymes toward substrates and/or difficulties in finding partnering enzymes with comparable substrate promiscuity 56

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Why Oral BPC-157 Works When Most Oral Peptides Don't Most therapeutic peptides cannot be taken orally because stomach acid and digestive enzymes (pepsin, trypsin) break them down before they reach the gut mucosa